New energy vehicles have a broad market, and the pricing and after-sales service of new energy vehicle enterprises have become the effective competitiveness of new energy vehicle enterprises. Therefore, this paper studies the pricing and after-sales service decision-making of new energy vehicles on the basis of game theory, and the study first gives a brief overview of game theory. Then, in the context of new energy vehicle subsidies, the optimal pricing under different sales modes is studied using game theory models. It also studies the utility of service stores of the same level of new energy vehicles with the support of game theory, and finally puts forward service suggestions from four aspects: optimizing offline service stores, expanding online services, developing service projects, and developing personalized services. This study can also provide valuable references for the pricing and service marketing of new energy vehicle enterprises, improve the competitiveness of after-sales service at the same time, and also put forward feasible suggestions for the future after-sales marketing methods of new energy vehicle manufacturers.