Let be distinct vertices of a multigraph with degrees and , respectively. The number of edge-disjoint -paths in is bounded above by . A multigraph is optimally edge-connected if for all pairs of distinct vertices and this upper bound is achieved. If is a multigraph with degree sequence , then we say is a realisation of . We characterise degree sequences of multigraphs that have an optimally edge-connected realisation as well as those for which every realisation is optimally edge-connected.