The planar Ramsey number PR(H1,H2) is the smallest integer n such that any planar graph on n vertices contains a copy of H1 or its complement contains a copy of H2. It is known that the Ramsey number R(K4–e,Kk–e) for k≤6. In this paper, we prove that PR(K4–e,K6–e)=16 and show the lower bounds on PR(K4–e,Kk–e).