The Wiener index, one of the oldest molecular topological descriptors used in mathematical chemistry, was well-studied during the past decades. For a graph , its Wiener index is defined as , where is the distance between two vertices and in . In this paper, we study the Wiener index of a class of composite graph, namely, double graph. We reveal the relation between the Wiener index of a given graph and the one of its double graph as well as the relation between Wiener index of a given graph and the one of its -iterated double graph. As a consequence, we determine the graphs with the maximum and minimum Wiener index among all double graphs and -iterated double graphs of connected graphs of the same order, respectively.