Let be a directed graph with vertices and edges. A function , where , is said to be a harmonious coloring of if for any two edges and of , the ordered pair . If the pair is not assigned, then is said to be a proper harmonious coloring of . The minimum is called the proper harmonious coloring number of . We investigate the proper harmonious coloring number of various graphs, including unidirectional paths, unicycles, inward-spoken (outward-spoken) wheels, -ary trees of different levels, and others.