Let be the eigenvalues of the sum-connectivity matrix of a graph . The sum-connectivity spectral radius of is the largest eigenvalue of its sum-connectivity matrix, and the sum-connectivity Estrada index of is defined as . In this paper, we obtain some results about the sum-connectivity spectral radius of graphs. In addition, we give some upper and lower bounds on the sum-connectivity Estrada index of graph , as well as some relations between and sum-connectivity energy. Moreover, we characterize that the star has maximum sum-connectivity Estrada index among trees on vertices.