For ω≤33, the known necessary conditions for existence of a (ν,{5,ω∗},1) PBD, namely ν,ω≡1mod4, ν≥4ω+1 and ν≡ω or 4ω+1mod20 are known to be sufficient in all but 26 cases. This paper provides several direct constructions which reduce the number of exceptions to 8.