Let be four type 1 matrices on the same group of order (odd) with the properties: (i) , , (ii) , and the diagonal elements are positive, (iii) , and (iv) . Call such matrices -matrices. If there exist circulant -matrices of order it can be easily shown that , where and are odd integers. It is known that they exist for odd , except for for which orders they can not exist. In this paper we give for the first time all non-equivalent circulant -matrices of odd order as well as some new non-equivalent circulant -matrices of order . We note that no -matrices were previously known for orders 31, 33, 37 and 41. These are presented in tables in the form of the corresponding non-equivalent supplementary difference sets. In the sequel we use -matrices and orthogonal designs.