We study nega-cyclic \(\pm 1\) matrices. We obtain preliminary results which are then used to decrease the search space. We find that there are \( 2 \), \( 4 \), \( 9 \), \( 23 \), \( 63 \), and \( 187 \) ip-equivalence classes for lengths \( 3 \), \( 5 \), \( 7 \), \( 9 \), \( 11 \), and \( 13 \) respectively. The matrices we find are used in a variant given here of the Goethals-Seidel array to form Hadamard matrices, the aim being to later check them for suitability for CDMA schemes.